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81.
《Ceramics International》2022,48(18):26378-26386
In this work different lead-free multilayered structures, composed of perovskite BaTiO3 and spinel NiFe2O4 thin layers, were obtained by solution deposition method. Structural characterization of the sintered thin films confirmed the well-defined layered structure with overall thickness from 160 to 600 nm, crystalline nature of perovskite BaTiO3 and spinel NiFe2O4 phases without secondary phases (after sintering below 900 °C) and grains on nanometer scale. Dielectric properties of the multiferroic multilayer BaTiO3/NiFe2O4 thin films were analyzed in temperature and frequency range from 30 °C to 200 °C and 100 Hz to 1 MHz, respectively. In comparison to the pure BaTiO3 films, the introduction of ferrite layer reduces dielectric response and increases low frequency permittivity dispersion of the multilayer thin films. The multilayer samples have shown relatively low dielectric loss with stronger contribution of conductivity at higher temperatures, and characteristic broad peak representing “relaxation” of the interface charge accumulation. 相似文献
82.
《Ceramics International》2022,48(1):744-753
The heat-resistance of the Cansas-II SiC/CVI-SiC mini-composites with a PyC and BN interface was studied in detail. The interfacial shear strength of the SiC/PyC/SiC mini-composites decreased from 15 MPa to 3 MPa after the heat treatment at 1500 °C for 50 h, while that of the SiC/BN/SiC mini-composites decreased from 248 MPa to 1 MPa, which could be mainly attributed to the improvement of the crystallization degree of the interface and the decomposition of the matrix. Aside from the above reasons, the larger declined fraction of the interfacial shear strength of the SiC/BN/SiC mini-composites might also be related to the gaps in the BN interface induced by the volatilization of B2O3·SiO2 phase, leading to a significant larger declined fraction of the tensile strength of the SiC/BN/SiC mini-composites due to the obvious expansion of the critical flaws on the fiber surface. Therefore, compared with the CVI BN interface, the CVI PyC interface has better heat-resistance at high temperatures up to 1500 °C due to the fewer impurities in PyC. 相似文献
83.
目的 为了提高糯米淀粉的粘度,以达到标签胶的要求。方法 对糯米淀粉进行丁二酸酐酯化改性,通过单因素试验及响应面优化确定出最佳酯化条件,测定其理化性质,并对其进行结构表征。结果 丁二酸酐酯化改性糯米淀粉的最优工艺条件:丁二酸酐添加量(丁二酸酐占淀粉干基的质量百分比)为10.3%,酯化温度为41.5℃,酯化时间为2.0 h,pH为9.0,在此条件下制得的糯米淀粉胶的粘度较高,可达到61.6 Pa·s,且溶解性与溶胀度均有不同程度的提高。电镜与热力学性质分析表明,酯化后淀粉颗粒结晶结构受到破坏,表面粗糙,出现凹陷与裂缝。结论 经过丁二酸酐酯化后,糯米淀粉胶的粘度得到提高。 相似文献
84.
《Advanced Powder Technology》2022,33(12):103847
We investigate synthesis, phase evolution, hollow and porous structure and magnetic properties of quasi-amorphous intermediate phase (QUAIPH) and hematite (α-Fe2O3) nanostructure synthesized by annealing of akaganeite (β-FeOOH) nanorods. It is found that the annealing temperature determines the phase composition of the products, the crystal structure/size dictates the magnetic properties whereas the final nanorod morphology is determined by the starting material. Annealing of β-FeOOH at ~300 °C resulted in the formation of hollow QUAIPH nanorods. The synthesized material shows low-cytotoxicity, superparamagnetism and good transverse relaxivity, which is rarely reported for QUAIPH. The QUAIPH nanorods started to transform to porous hematite nanostructures at ~350 °C and phase transformation was completed at 600 °C. During the annealing, the crystal structure changed from monoclinic (akaganeite) to quasi-amorphous and rhombohedral (hematite). Unusually, the crystallite size first decreased (akaganeite → QUAIPH) and then increased (QUAIPH → hematite) during annealing whereas the nanorods retained particle shape. The magnetic properties of the samples changed from antiferromagnetic (akaganeite) to superparamagnetic with blocking temperature TB = 84 K (QUAIPH) and finally to weak-ferromagnetic with the Morin transition at TM = 244 K and high coercivity HC = 1652 Oe (hematite). The low-cytotoxicity and MRI relaxivity (r2 = 5.80 mM?1 s?1 (akaganeite), r2 = 4.31 mM?1 s?1 (QUAIPH) and r2 = 5.17 mM?1 s?1 (hematite)) reveal potential for biomedical applications. 相似文献
85.
《International Journal of Hydrogen Energy》2022,47(34):15480-15490
The rapid increase in energy consumption has severely rehabilitated human life urging to develop reliable and environmental friendly energy storage devices. Target oriented, systematic approach has been adopted to synthesis La doped CeO2 nanostructures with percentage as LaxCe1-xO2 (X = 0,1,3,5,7) for potential super capacitors applications. Morphological doping impact on H2 production, electrochemical and optical properties are thoroughly investigated. XRD studies revealed the crystalline phase purity and attained approximately 35 nm average crystallite size. The SEM images exposed that primary morphology nano-particles has been tuned into nanorods by increasing the La concentration in CeO2 with size range 40~60 nm. CV graphs depicted that the prepared electrodes obey the pseudo capacitive faradaic reactions behavior in nature. Maximum capacitance (925 F g-1) has been achieved by La0·05Ce0·95O2 which is better than numerous reported materials. The La0·05Ce0·95O2 also exhibited excellent GCD stability with 87.8% retention exhibiting it suitability for supercapacitor applications. Furthermore, the La0·05Ce0·95O2 showed the significantly higher H2 (9 μmol h?1g?1) production rate as compared to undoped CeO2 and La0·01Ce0·99O2, La0·03Ce0·97O2 samples. This higher production is attributed to the recombination rate and have strong substantial correlation with optical characteristics. 相似文献
86.
《International Journal of Hydrogen Energy》2022,47(64):27481-27492
Photocatalytic water splitting has become a promising technology to solve environmental pollution and energy shortage. Exploring stable and efficient photocatalysts are highly desired. Herein, we propose novel low-dimensional InSbS3 semiconductors with good stability based on density functional theory. Such InSbS3 structures could be obtained from their bulk crystal by suitable exfoliation methods. Our calculations indicate that two-dimensional (2D) and one-dimensional (1D) InSbS3 nanostructures have moderate band gaps (2.54 and 1.97 eV, respectively) and suitable band edge alignments, which represents sufficient redox capacity for photocatalytic water splitting. 2D InSbS3 monolayer possesses oxygen evolution reaction (OER) activity and 1D InSbS3 single-nanochain possesses hydrogen evolution reaction (HER) activity under acidic conditions. Interestingly, two edge electron states can be introduced when the dimension of InSbS3 is reduced from 2D to 1D and the new electron states can exist in arbitrary-width nanoribbons, which can effectively promote the process of HER. Moreover, InSbS3 monolayer and single-nanochain also exhibit large solar-to-hydrogen efficiency, high carrier mobility, and excellent optical absorption properties, which can facilitate the process of photocatalytic reactions. Our findings can stimulate the synthesis and applications of low-dimensional InSbS3 semiconductors for overall water splitting. 相似文献
87.
Yuhang Xing Ruyi Li Lu Xue Mianhong Chen Xuli Lu Zhihao Duan Wei Zhou Jihua Li 《International Journal of Food Science & Technology》2022,57(8):5268-5279
Mangiferin (MGF) is a phenolic compound isolated from mango, but its poor solubility significantly limits its use. In this study, MGF was embedded into the inner aqueous phase of W1/O/W2 emulsions. Firstly, the dissolution method of MGF was determined. MGF remained stable in solution with pH 13 at 30 min, and its solubility reached 10 mg mL−1. When the pH of MGF solutions was adjusted from pH 13 to pH 6, MGF did not immediately crystallise, providing sufficient time to construct the MGF-loaded W1/O/W2 emulsions. Subsequently, the MGF-loaded W1/O/W2 emulsions were constructed using polyglycerol polyricinoleate (PGPR) and calcium caseinate (CAS). The formation and stability of the W1/O/W2 emulsions were investigated. The MGF-loaded W1/O/W2 emulsions stabilised with 1% PGPR and 1% – 3% CAS exhibited a low viscosity, limited loading capacity, and poor stability. Conversely, the MGF-loaded W1/O/W2 emulsions stabilised by 3%PGPR–3%CAS exhibited optimal loading capacity (encapsulation efficiency = 95.31% and loading efficiency = 0.91%) and stability, which was attributed to the fact that high viscosity and gel state retarded the migration of inner aqueous phase. These results indicated that the W1/O/W2 emulsions stabilised by PGPR and CAS may be a potential alternative for encapsulating mangiferin. 相似文献
88.
Zinovi Dashevsky Ihor Horichok Mykola Maksymuk Ahmad Rifqi Muchtar Bhuvanesh Srinivasan Takao Mori 《Journal of the American Ceramic Society》2022,105(6):4500-4511
GeTe is a promising candidate for the fabrication of high-temperature segments for p-type thermoelectric (TE) legs. The main restriction for the widespread use of this material in TE devices is high carrier concentration (up to ∼ 1021 cm−3), which causes the low Seebeck coefficient and high electronic component of thermal conductivity. In this work, the band structure diagram and phase equilibria data have been effectively used to attune the carrier concentration and to obtain the high TE performance. The Ge1−xBixTe (x = 0.04) material prepared by the Spark plasma sintering (SPS) technique demonstrates a high power factor accompanied by moderate thermal conductivity. As a result, a significantly higher dimensionless TE figure of merit ZT = 2.0 has been obtained at ∼ 800 K. Moreover, we are the first to propose that application of the developed Ge1−xBixTe (x = 0.04) material in the TE unicouple should be accompanied by SnTe and CoGe2 transition layers. Only such a unique solution for the TE unicouple makes it possible to prevent the negative effects of high contact resistance and chemical diffusion between the segments at high temperatures. 相似文献
89.
90.
《Ceramics International》2022,48(7):9324-9329
(K,Na)NbO3 (KNN)-based ceramics have been proven to be formidable candidates among lead-free piezoelectric materials, yet poor reproducibility always hinders their progress. In the present study, the effects of low lithium substitution on the electrical properties and microstructure of (K0.5Na0.5)1-xLixNbO3 (KNLN) ceramics were investigated. All samples were synthesized by the sol-gel method. The Curie temperature (TC) of the ceramics shifted to higher temperature and gradually decreased the monoclinic-tetragonal (TM-T) phase transition. Li+ substitution had a prominent effect on the ferroelectric properties and improved the piezoelectric coefficient (d33) up to 181 pC/N. X-Ray Diffraction (XRD) studies and Field Emission Scanning Electron Microscopy (FESEM) images revealed an inevitable tetragonal tungsten bronze (TTB) secondary phase, which was formed during the preparation process. It was demonstrated that the volatilization of Li+ cations facilitated TTB growth. The coexistence of two different phase structures proved to enhance the KNN piezoelectric performance. 相似文献